Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. Failure of 321 stainless steel heater tube in heavy crude oil. The cracking was found when rust stainingleaks were observed. Steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Why does chloride stress corrosion cracking and pascc only. Effect of polythionic acid concentration on stress. Apr 29, 2016 stress corrosion cracking of gas pipelines 3 minute 2014 thesis finalist duration. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Stress corrosion cracking issues in syngas plants that may be. Effect of polythionic acid concentration on stress corrosion. Effects of sensitization and service fluid chemistry on. Rp017097 polythionic stress corrosion cracking protection. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. Pta scc is also covered by nace standard rp017097, protection of. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking. However, in some instances, stabilized austenitic sss have been found to be susceptible to pitting, crevice. These characteristics are consistent with stress corrosion cracking due to polythionic acids. The item was exposed to sulfur containing natural gas in a continuous flare. Sp04032015, avoiding caustic stress corrosion cracking of refinery equipment and piping sp01142014sg, refinery injection and process mix points sp0170hd2012sg protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Ctlpolythionic stress corrosion cracking of stainless. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress. What are the industrial practices being followed in. The temperature of the column in the region of the cracking is approximately 70c 158f. Stress corrosion cracking susceptibility of stainless.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Effect of carbon content on polythionic acid stress corrosion. For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Cracking of sensitized stainless steels inspectioneering. Nace rp0170 protection of austenitic stainless steels. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Polythionic acid stress corrosion cracking of type 310 stainless steel. Precautions to avoid polythionic acid stress corrosion. Stress corrosion cracking susceptibility of stainless steels. Polythionic acid stress corrosion cracking pascc in stainless steel is a downtime phenomenon. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure.
For heaters with stainless steel tubes, an evaluation should be made to determine their susceptibility to internal and external pascc. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. Nace rp0170 protection of austenitic stainless steels and. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by. An austenitic stainless steel for sulfuric acid corrosion environments. Complete document protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment view abstract product details detail summary view all details. Stress corrosion cracking of gas pipelines 3 minute 2014 thesis finalist duration. Stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0. Results reveal that the stress corrosion life decreases rapidly on increasing the concentration from 0. Nace sp0170 protection of austenitic stainless steels and. All of the cracks observed were found underneath the coke deposits.
If deemed necessary, specific steps should be taken to prevent cracking during downtime. Standard recommended practice austenitic stainless steels and. Sulfur can come from feed stock, additives or fuels. Polythionic stress corrosion cracking of stainless steel tube. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Stress corrosion cracking and component failure 169. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Protection of austenitic stainless steels and other. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid.
This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen air and water. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Nace sp01702018 protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Jan 05, 2016 polythionic acid neutralization and decontamination process. Resistant to chloride and polythionic acid stress corrosion cracking. The terminology sensitization, which is generally used to discuss intergranular corrosion cracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test. Stress corrosion cracking by krittin rattakham youtube.
Depletion of cr in steels promotes corrosion adjacent to grain boundaries. Abstract polythionic acid stress corrosion cracking pta scc of. Whereas 9cr is immune to scc, chlorides in the presence of water may cause scc of any 300 ss piping at temperatures above about 140. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Polythionic acid stress corrosion cracking in heater pipes. Stress corrosion cracking scc caused by polythionic acid andor chlorides has occurred in coal liquefaction pilot plants. The stress corrosion cracking sco of sensitized type 304 stainless steel in thiosulfate. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Results show that alloys 304 and 304l, in the solution. Overview of polythionic acid stress corrosion cracking pascc. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. The terminology sensitization, which is generally used to discuss intergranular corrosioncracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Polythionic acid neutralization and decontamination process. Nacesp0170 protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment nacesp0170 2018 edition current show complete document history. The cracks are intergranular and narrow with no significant branching. Nace standard practice0170 will be helpful to understand the.
Stress corrosion cracking scc may be defined as the delayed failure of alloys by. Nacesp0170 protection of austenitic stainless steels. Dtn170 stainless steel protector delta tech service, inc. Dtn170 stainless steel protector dtn170 is a mixture of low chloride soda ash, stainless steel stress cracking inhibitor and surfactant when mixed with low chloride water will meet the nace rp017097 standard for protection of austenitic stainless steel from polythionic acid stress corrosion cracking during shutdown of refinery equipment. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Pdf polythionic acid corrosion in refinery hydroprocessors. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Stresscorrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. Unless suitable precautions are taken, in accordance with nace rp0170 nace, 1997. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. Nace sp0170 protection of austenitic stainless steels. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. Stress corrosion cracking issues in syngas plants that may. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist.
Stabilized austenitic stainless steels sss have since been widely used in the petroleum refining industry because of their resistance to sulphidic corrosion and polythionic acid stress corrosion cracking scc, as well as of their excellent strength and toughness. Rp017097 polythionic stress corrosion cracking protection free download as pdf file. Chemical studies of polythionic acid stresscorrosion cracking. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc.
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